If the interface of the vmware machine is bridged, you should be able to see it in the same way as any other physical machine. If your vm machine is using NAT to cross the host machine's physical interface, then it is the physical machine mac you should be looking for.
Yes, my vmware machine is bridged and I have individual IP & Mac.
but knowing nothing about the actual machine where the vmware is installed,
is there any possibility to view switch port where it is connected.