Sudo question

Hello, I would like to know what should I put on the sudoers file to block a determined group os using just one specific command as root?
He can do anything, but not execute program X, how can I do this?

Thank you very much.

By using the ! and the program you don't want to run...BUT,

Suggest you look at the options available and do it a different way.
sudoers manual

Thank you very much.