If you edit the file and insert this, how will the file be unzipped later? gunzip will expect the content in specific locations that it controls and I would not rely on the extracted files. How would you expect gunzip to deal with this extra data?
What's the overall intention? Are you trying to edit the content of one of the zipped files somehow?
By the way, my intention to do this is to have a header for the delivery protocol - within this header (the ascii string) are infos for the delivery tool (i.e. the recipient). When the recipient will get this file, before the uncompressing he has to delete the header first...