Hi.
Is Linux running in a virtual machine, or on the physical hardware?
Assuming the latter, it's likely that the remaining ~450 GB is unpartitioned, depending on what options you selected during the installation.
You can check in fdisk, or the graphical palimpsest partitioning tool, if you prefer. You can create a new partition of the required size.
For example, here's an example where I've created a new partition of 5GB from unpartitioned space on /dev/sda, using fdisk:
[root@admin ~]# fdisk -uc /dev/sda
Command (m for help): p
Disk /dev/sda: 21.5 GB, 21474836480 bytes
255 heads, 63 sectors/track, 2610 cylinders, total 41943040 sectors
Units = sectors of 1 * 512 = 512 bytes
Sector size (logical/physical): 512 bytes / 512 bytes
I/O size (minimum/optimal): 512 bytes / 512 bytes
Disk identifier: 0x0003bc8c
Device Boot Start End Blocks Id System
/dev/sda1 * 2048 1026047 512000 83 Linux
/dev/sda2 1026048 13314047 6144000 8e Linux LVM
Command (m for help): n
Command action
e extended
p primary partition (1-4)
p
Partition number (1-4): 3
First sector (13314048-41943039, default 13314048): (pressed Enter to accept default)
Using default value 13314048
Last sector, +sectors or +size{K,M,G} (13314048-41943039, default 41943039): +5G
Command (m for help): p
Disk /dev/sda: 21.5 GB, 21474836480 bytes
255 heads, 63 sectors/track, 2610 cylinders, total 41943040 sectors
Units = sectors of 1 * 512 = 512 bytes
Sector size (logical/physical): 512 bytes / 512 bytes
I/O size (minimum/optimal): 512 bytes / 512 bytes
Disk identifier: 0x0003bc8c
Device Boot Start End Blocks Id System
/dev/sda1 * 2048 1026047 512000 83 Linux
/dev/sda2 1026048 13314047 6144000 8e Linux LVM
/dev/sda3 13314048 23799807 5242880 83 Linux
Command (m for help): t
Partition number (1-4): 3
Hex code (type L to list codes): 8e
Changed system type of partition 3 to 8e (Linux LVM)
Command (m for help): p
Disk /dev/sda: 21.5 GB, 21474836480 bytes
255 heads, 63 sectors/track, 2610 cylinders, total 41943040 sectors
Units = sectors of 1 * 512 = 512 bytes
Sector size (logical/physical): 512 bytes / 512 bytes
I/O size (minimum/optimal): 512 bytes / 512 bytes
Disk identifier: 0x0003bc8c
Device Boot Start End Blocks Id System
/dev/sda1 * 2048 1026047 512000 83 Linux
/dev/sda2 1026048 13314047 6144000 8e Linux LVM
/dev/sda3 13314048 23799807 5242880 8e Linux LVM
Command (m for help): w
The partition table has been altered!
Calling ioctl() to re-read partition table.
Everything I typed is in red. You'll need to reboot to update the partition table.
Now run these commands, substituting volume, volume group, logical volume names and sizes for your own:
[root@admin ~]# pvcreate /dev/sda3 # <-- for me this is what is new, in blue, above
Physical volume "/dev/sda3" successfully created
[root@admin ~]# vgextend rootvg /dev/sda3
Volume group "rootvg" successfully extended
[root@admin ~]# pvs
PV VG Fmt Attr PSize PFree
/dev/sda2 rootvg lvm2 a-- 5.84g 320.00m
/dev/sda3 rootvg lvm2 a-- 4.97g 4.97g
/dev/sdb dist01vg lvm2 a-- 20.00g 0
[root@admin ~]# vgdisplay -s
"dist01vg" 20.00 GiB [20.00 GiB used / 0 free]
"rootvg" 10.81 GiB [5.53 GiB used / 5.28 GiB free]
[root@admin ~]#
[root@admin ~]# lvextend -L+5G /dev/mapper/rootvg-rootlv # <-- You can substitute -l+100%FREE for -L+5G if there isn't quite 5GB of free space
Extending logical volume rootlv to 9.03 GiB
Logical volume rootlv successfully resized
[root@admin ~]# resize2fs /dev/mapper/rootvg-rootlv
resize2fs 1.41.12 (17-May-2010)
Filesystem at /dev/mapper/rootvg-rootlv is mounted on /; on-line resizing required
old desc_blocks = 1, new_desc_blocks = 1
Performing an on-line resize of /dev/mapper/rootvg-rootlv to 2367488 (4k) blocks.
The filesystem on /dev/mapper/rootvg-rootlv is now 2367488 blocks long.
If Linux is running in a virtual machine, you should add a new hard disk, then run the same commands for (probably) /dev/sdb.